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1 | (38) |
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Why Care about Chemistry? |
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2 | (1) |
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3 | (2) |
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5 | (1) |
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Identifying Matter: Physical Properties |
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6 | (5) |
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Chemical Changes and Chemical Properties |
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11 | (2) |
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Classifying Matter: Substances and Mixtures |
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13 | (2) |
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Classifying Matter: Elements and Compounds |
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15 | (2) |
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Nanoscale Theories and Models |
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17 | (4) |
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21 | (2) |
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23 | (4) |
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Communicating Chemistry: Symbolism |
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27 | (2) |
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29 | |
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20 | (19) |
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Portrait of a Scientist John Dalton |
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22 | (1) |
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Estimation How Tiny Are Atoms and Molecules? |
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23 | (4) |
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Portrait of a Scientist Sir Harold Kroto |
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27 | (12) |
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39 | (38) |
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Atomic Structure and Subatomic Particles |
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40 | (3) |
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43 | (1) |
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The Sizes of Atoms and the Units Used to Represent Them |
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44 | (6) |
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Uncertainty and Significant Figures |
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50 | (3) |
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Atomic Numbers and Mass Numbers |
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53 | (3) |
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Isotopes and Atomic Weight |
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56 | (3) |
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Amounts of Substances: The Mole |
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59 | (1) |
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Molar Mass and Problem Solving |
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60 | (2) |
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62 | (2) |
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Portrait of a Scientist Ernest Rutherford |
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44 | (2) |
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Tools of Chemistry Scanning Tunneling Microscopy |
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46 | (8) |
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Tools of Chemistry Mass Spectrometer |
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54 | (6) |
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Estimation The Size of Avogadro's Number |
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60 | (2) |
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Portrait of a Scientist Dmitri Mendeleev |
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62 | (2) |
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64 | (2) |
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Running Out of an Element? |
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66 | (11) |
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Chemistry You Can Do Preparing a Pure Sample of an Element |
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68 | (9) |
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77 | (46) |
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78 | (3) |
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Naming Binary Inorganic Compounds |
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81 | (2) |
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83 | (2) |
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Alkanes and Their Isomers |
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85 | (3) |
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88 | (6) |
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Naming Ions and Ionic Compounds |
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94 | (3) |
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Properties of Ionic Compounds |
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97 | (3) |
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100 | (4) |
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104 | (2) |
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Determining Empirical and Molecular Formulas |
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106 | (2) |
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The Biological Periodic Table |
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108 | (3) |
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Biomolecules: Carbohydrates and Fats |
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111 | |
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Estimation Number of Alkane Isomers |
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86 | (24) |
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Chemistry You Can Do Pumping Iron: How Strong Is Your Breakfast Cereal? |
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110 | (1) |
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110 | (13) |
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Quantities of Reactants and Products |
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123 | (41) |
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124 | (2) |
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Patterns of Chemical Reactions |
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126 | (7) |
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Balancing Chemical Equations |
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133 | (3) |
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The Mole and Chemical Reactions: The Macro-Nano Connection |
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136 | (5) |
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Reactions with One Reactant in Limited Supply |
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141 | (5) |
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Evaluating the Success of a Synthesis: Percent Yield |
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146 | (4) |
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Percent Composition and Empirical Formulas |
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150 | (14) |
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Portrait of a Scientist Antoine Lavoisier |
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125 | (5) |
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Portrait of a Scientist Alfred Nobel |
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130 | (12) |
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Estimation How Much CO2 Is Produced by Your Car? |
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142 | (5) |
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Chemistry You Can Do Vinegar and Baking Soda: A Stoichiometry Experiment |
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147 | (17) |
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164 | (50) |
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Exchange Reactions: Precipitation and Net Ionic Equations |
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165 | (7) |
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Acids, Bases, and Acid-Base Exchange Reactions |
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172 | (9) |
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Oxidation-Reduction Reactions |
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181 | (4) |
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Oxidation Numbers and Redox Reactions |
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185 | (3) |
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Displacement Reactions, Redox, and the Activity Series |
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188 | (4) |
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192 | (6) |
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Molarity and Reactions in Aqueous Solutions |
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198 | (4) |
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Aqueous Solution Titrations |
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202 | (12) |
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Chemistry You Can Do Pennies, Redox, and the Activity Series of Metals |
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192 | (7) |
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Chemistry in the News Solving a Problem in Industrial Chemistry |
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199 | (15) |
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Energy and Chemical Reactions |
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214 | (58) |
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215 | (3) |
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218 | (5) |
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223 | (5) |
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228 | (5) |
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233 | (2) |
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Enthalpy Changes for Chemical Reactions |
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235 | (5) |
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Where Does the Energy Come From? |
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240 | (2) |
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Measuring Enthalpy Changes: Calorimetry |
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242 | (4) |
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246 | (2) |
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Standard Molar Enthalpies of Formation |
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248 | (5) |
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Chemical Fuels for Home and Industry |
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253 | (3) |
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Foods: Fuels for Our Bodies |
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256 | (16) |
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Portrait of a Scientist James P. Joule |
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216 | (2) |
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Estimation Earth's Kinetic Energy |
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218 | (16) |
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Chemistry You Can Do Work and Volume Change |
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234 | (5) |
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Chemistry You Can Do Rusting and Heating |
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239 | (16) |
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Chemistry in the News Can Hydrogen Be Stored in Tiny Tanks? |
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255 | (17) |
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Electron Configurations and the Periodic Table |
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272 | (57) |
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Electromagnetic Radiation and Matter |
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273 | (2) |
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275 | (5) |
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The Bohr Model of the Hydrogen Atom |
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280 | (5) |
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Beyond the Bohr Model: The Quantum Mechanical Model of the Atom |
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285 | (3) |
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Quantum Numbers, Energy Levels, and Orbitals |
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288 | (6) |
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Atom Electron Configurations |
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294 | (7) |
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Ion Electron Configurations |
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301 | (6) |
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Periodic Trends: Atomic Radii |
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307 | (3) |
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Periodic Trends: Ionic Radii |
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310 | (2) |
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Periodic Trends: Ionization Energies |
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312 | (3) |
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Periodic Trends: Electron Affinities |
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315 | (1) |
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Ion Formation and Ionic Compounds |
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316 | (1) |
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Energy Considerations in Ionic Compound Formation |
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317 | (12) |
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277 | (7) |
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Portrait of a Scientist Niels Bohr |
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284 | (1) |
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Chemistry You Can Do Using a Compact Disc as a Diffraction Grating |
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285 | (2) |
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Chemistry in the News Protons: What Shape? |
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287 | (17) |
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Tools of Chemistry Nuclear Magnetic Resonance and Its Applications |
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304 | (25) |
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329 | (54) |
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330 | (2) |
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Single Covalent Bonds and Lewis Structures |
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332 | (5) |
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Single Covalent Bonds in Hydrocarbons |
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337 | (3) |
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340 | (3) |
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Multiple Covalent Bonds in Hydrocarbons |
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343 | (5) |
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Bond Properties: Bond Length and Bond Energy |
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348 | (6) |
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Bond Properties: Bond Polarity and Electronegativity |
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354 | (3) |
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357 | (2) |
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Lewis Structures and Resonance |
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359 | (4) |
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Exceptions to the Octet Rule |
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363 | (4) |
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367 | (2) |
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369 | (14) |
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Portrait of a Scientist Gilbert Newton Lewis |
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332 | (8) |
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Chemistry in the News Keeping Cool, but Safely |
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340 | (10) |
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Chemistry in the News Trans Fatty Acids |
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350 | (6) |
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Portrait of a Scientist Linus Pauling |
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356 | (10) |
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Chemistry in the News Biologically Reactive Oxygen and Antioxidants |
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366 | (17) |
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383 | (51) |
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384 | (1) |
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Predicting Molecular Shapes: VSEPR |
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385 | (13) |
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Orbitals Consistent with Molecular Shapes: Hybridization |
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398 | (5) |
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Hybridization in Molecules with Multiple Bonds |
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403 | (2) |
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405 | (4) |
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Noncovalent Interactions and Forces between Molecules |
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409 | (9) |
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Biomolecules: DNA and the Importance of Molecular Structure |
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418 | (4) |
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422 | |
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Tools of Chemistry Infrared Spectroscopy |
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394 | (3) |
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397 | (24) |
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Tools of Chemistry Ultraviolet-Visible Spectroscopy |
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408 | (9) |
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Chemistry You Can Do Molecular Structure and Biological Activity |
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417 | (1) |
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Portrait of a Scientist Rosalind Franklin |
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418 | (3) |
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421 | (13) |
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Estimation Base Pairs and DNA |
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422 | (12) |
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434 | (53) |
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435 | (1) |
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436 | (5) |
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441 | (3) |
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The Behavior of Ideal Gases |
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444 | (6) |
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450 | (4) |
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Quantities of Gases in Chemical Reactions |
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454 | (3) |
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Gas Density and Molar Masses |
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457 | (2) |
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Gas Mixtures and Partial Pressures |
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459 | (5) |
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The Behavior of Real Gases |
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464 | (3) |
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Chemical Reactions in the Atmosphere |
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467 | (1) |
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Ozone and Stratospheric Ozone Depletion |
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468 | (3) |
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Chemistry and Pollution in the Troposphere |
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471 | (2) |
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Estimation Thickness of Earth's Atmosphere |
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437 | (11) |
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Portrait of a Scientist Jacques Alexandre Cesar Charles |
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448 | (10) |
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Estimation Helium Balloon Buoyancy |
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458 | (11) |
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Portrait of a Scientist F. Sherwood Rowland |
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469 | (1) |
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Portrait of a Scientist Susan Solomon |
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470 | (2) |
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Chemistry You Can Do Particle Size and Visibility |
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472 | (1) |
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473 | (14) |
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Liquids, Solids, and Materials |
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487 | (57) |
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488 | (3) |
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491 | (3) |
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Phase Changes: Solids, Liquids, and Gases |
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494 | (11) |
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Water: An Important Liquid with Unusual Properties |
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505 | (3) |
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508 | (3) |
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511 | (7) |
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518 | (1) |
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519 | (4) |
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Metals, Semiconductors, and Insulators |
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523 | (5) |
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528 | (3) |
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Cement, Ceramics, and Glass |
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531 | |
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506 | (38) |
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Chemistry You Can Do Melting Ice with Pressure |
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508 | (8) |
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Chemistry You Can Do Closest Packing of Spheres |
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516 | (3) |
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Portrait of a Scientist Dorothy Crowfoot Hodgkin |
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519 | (1) |
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Tools of Chemistry X-Ray Crystallography |
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520 | (24) |
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Fuels, Organic Chemicals, and Polymers |
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544 | (64) |
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545 | (8) |
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553 | (2) |
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555 | (3) |
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Atmospheric Carbon Dioxide, the Greenhouse Effect, and Global Warming |
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558 | (5) |
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563 | (1) |
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Alcohols and Their Oxidation Products |
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564 | (8) |
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Carboxylic Acids and Esters |
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572 | (4) |
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Synthetic Organic Polymers |
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576 | (15) |
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Biopolymers: Proteins and Polysaccharides |
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591 | (17) |
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Chemistry in the News Striking Diamonds in Oil |
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549 | (5) |
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Tools of Chemistry Gas Chromatography |
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554 | (4) |
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558 | (14) |
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Portrait of a Scientist Percy Lavon Julian |
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572 | (11) |
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Chemistry You Can Do Making ``Gluep'' |
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583 | (6) |
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Portrait of a Scientist Stephanie Louise Kwolek |
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589 | (19) |
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Chemical Kinetics: Rates of Reactions |
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608 | (62) |
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609 | (6) |
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Effect of Concentration on Reaction Rate |
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615 | (4) |
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Rate Law and Order of Reaction |
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619 | (6) |
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A Nanoscale View: Elementary Reactions |
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625 | (6) |
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Temperature and Reaction Rate: The Arrhenius Equation |
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631 | (4) |
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Rate Laws for Elementary Reactions |
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635 | (2) |
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637 | (5) |
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Catalysts and Reaction Rate |
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642 | (3) |
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Enzymes: Biological Catalysts |
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645 | (7) |
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652 | (18) |
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Chemistry You Can Do Simulating First-Order and Zeroth-Order Reactions |
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622 | (3) |
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Estimation Pesticide Decay |
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625 | (3) |
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Chemistry You Can Do Kinetics and Vision |
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628 | (3) |
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Portrait of a Scientist Ahmed H. Zewail |
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631 | (16) |
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Chemistry You Can Do Enzymes: Biological Catalysts |
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647 | (4) |
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Chemistry in the News Protease Inhibitors and AIDS |
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651 | (19) |
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670 | (47) |
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Characteristics of Chemical Equilibrium |
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671 | (3) |
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674 | (8) |
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Determining Equilibrium Constants |
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682 | (4) |
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The Meaning of the Equilibrium Constant |
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686 | (2) |
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Using Equilibrium Constants |
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688 | (6) |
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Shifting a Chemical Equilibrium: Le Chatelier's Principle |
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694 | (7) |
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Equilibrium at the Nanoscale |
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701 | (2) |
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Controlling Chemical Reactions: The Haber-Bosch Process |
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703 | (14) |
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Chemistry in the News Equilibrium and Alzheimer's Disease |
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673 | (26) |
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Estimation Generating Gaseous Fuel |
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699 | (4) |
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Portrait of a Scientist Fritz Haber |
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703 | (14) |
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The Chemistry of Solutes and Solutions |
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717 | (47) |
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Solubility and Intermolecular Forces |
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718 | (6) |
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Enthalpy, Entropy, and Dissolving Solutes |
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724 | (1) |
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Solubility and Equilibrium |
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725 | (3) |
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Temperature and Solubility |
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728 | (2) |
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Pressure and Dissolving Gases in Liquids: Henry's Law |
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730 | (2) |
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Solution Concentration: Keeping Track of Units |
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732 | (7) |
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Vapor Pressures, Boiling Points, and Freezing Points of Solutions |
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739 | (7) |
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Osmotic Pressure of Solutions |
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746 | (4) |
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750 | (1) |
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751 | (2) |
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Water: Natural, Clean, and Otherwise |
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753 | (11) |
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Chemistry in the News Bubbling Away: Delicate and Stout |
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731 | (14) |
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Portrait of a Scientist Jacobus Henricus van't Hoff |
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745 | (7) |
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Chemistry You Can Do Curdled Colloids |
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752 | (12) |
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764 | (52) |
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The Brønsted-Lowry Concept of Acids and Bases |
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765 | (6) |
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Carboxylic Acids and Amines |
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771 | (2) |
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The Autoionization of Water |
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773 | (2) |
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775 | (4) |
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Ionization Constants of Acids and Bases |
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779 | (5) |
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Molecular Structure and Acid Strength |
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784 | (5) |
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Problem Solving Using Ka and Kb |
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789 | (5) |
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Acid-Base Reactions of Salts |
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794 | (6) |
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800 | (2) |
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Practical Acid-Base Chemistry |
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802 | |
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Portrait of a Scientist Arnold Beckman |
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777 | (1) |
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Chemistry in the news How Low Can You Go? Ultraacidic Water |
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777 | (39) |
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Estimation Using an Antacid |
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805 | (3) |
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Chemistry You Can Do Aspirin and Digestion |
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808 | (8) |
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Additional Aqueous Equilibria |
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816 | (41) |
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817 | (11) |
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828 | (8) |
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836 | (1) |
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Solubility Equilibria and the Solubility Product Constant, Ksp |
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837 | (3) |
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Factors Affecting Solubility |
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840 | (7) |
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Precipitation: Will It Occur? |
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847 | (10) |
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Thermodynamics: Directionality of Chemical Reactions |
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857 | (51) |
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Reactant-Favored and Product-Favored Processes |
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858 | (1) |
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Chemical Reactions and Dispersal of Energy |
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859 | (2) |
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Measuring Dispersal of Energy: Entropy |
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861 | (6) |
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Calculating Entropy Changes |
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867 | (1) |
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Entropy and the Second Law of Thermodynamics |
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867 | (5) |
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872 | (4) |
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Gibbs Free Energy Changes and Equilibrium Constants |
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876 | (6) |
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Gibbs Free Energy, Maximum Work, and Energy Resources |
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882 | (3) |
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Gibbs Free Energy and Biological Systems |
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885 | (7) |
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Conservation of Gibbs Free Energy |
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892 | (2) |
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Thermodynamic and Kinetic Stability |
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894 | |
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Portrait of a Scientist Ludwig Boltzmann |
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862 | (8) |
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Chemistry You Can Do Rubber Bands and Thermodynamics |
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870 | (14) |
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Chemistry in the news The Hindenburg Disaster--- Hydrogen or Thermite? |
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884 | (24) |
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Estimation Gibbs Free Energy and Automobile Travel |
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894 | (14) |
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Electrochemistry and Its Applications |
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908 | (56) |
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909 | (2) |
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Using Half-Reactions to Understand Redox Reactions |
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911 | (6) |
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917 | (4) |
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Electrochemical Cells and Voltage |
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921 | (5) |
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Using Standard Cell Potentials |
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926 | (4) |
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930 | (4) |
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Effect of Concentration on Cell Potential |
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934 | (4) |
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938 | (3) |
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941 | (4) |
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945 | (2) |
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Electrolysis---Forcing Reactant-Favored Reactions to Occur |
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947 | (3) |
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950 | (3) |
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Corrosion---Product-Favored Reactions |
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953 | |
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Chemistry You Can Do Remove Tarnish the Easy Way |
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928 | (3) |
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Portrait of a Scientist Michael Faraday |
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931 | (11) |
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Portrait of a Scientist Wilson Greatbatch |
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942 | (3) |
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945 | (19) |
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Estimation The Cost of Aluminum in a Soda Can |
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953 | (11) |
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964 | (38) |
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The Nature of Radioactivity |
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965 | (1) |
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966 | (4) |
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Stability of Atomic Nuclei |
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970 | (5) |
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Rates of Disintegration Reactions |
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975 | (7) |
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Artificial Transmutations |
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982 | (1) |
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983 | (5) |
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988 | (1) |
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Nuclear Radiation: Effects and Units |
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989 | (3) |
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Applications of Radioactivity |
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|
992 | |
|
Portrait of a Scientist Glenn Seaborg |
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982 | (1) |
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Portrait of a Scientist Darleane C. Hoffmann |
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|
983 | (4) |
|
Building a Repository for High-Level Nuclear Waste |
|
|
987 | (15) |
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Chemistry You Can Do Counting Millirems: Your Radiation Exposure |
|
|
991 | (11) |
|
The Chemistry of the Main Group Elements |
|
|
1002 | (43) |
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Formation of the Elements |
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1003 | (2) |
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1005 | (5) |
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Some Main Group Elements Extracted by Physical Methods: Nitrogen, Oxygen, and Sulfur |
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1010 | (2) |
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Some Main Group Elements Extracted by Electrolysis: Sodium, Chlorine, Magnesium, and Aluminum |
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1012 | (5) |
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Some Main Group Elements Extracted by Chemical Oxidation-Reduction: Phosphorus, Bromine, and Iodine |
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1017 | (3) |
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A Periodic Perspective: The Main Group Elements |
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1020 | (11) |
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Portrait of a Scientist Charles Martin Hall |
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1017 | (3) |
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Portrait of a Scientist Herbert H. Dow |
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1020 | (11) |
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Ammonia Synthesis under Mild Conditions |
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1031 | (14) |
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Chemistry of Selected Transition Elements and Coordination Compounds |
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1045 | |
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Properties of the Transition (d-Block) Elements |
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1046 | (5) |
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Iron and Steel: The Use of Pyrometallurgy |
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1051 | (4) |
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1055 | (4) |
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Silver and Gold: The Other Coinage Metals |
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1059 | (2) |
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1061 | (3) |
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Coordinate Covalent Bonds: Complex Ions and Coordination Compounds |
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1064 | (11) |
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Crystal-Field Theory: Color and Magnetism in Coordination Compounds |
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1075 | |
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Estimation Up and Down the East Coast |
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1053 | (7) |
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The Sacagawea Dollar Coin: In Search of Gold |
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1060 | |
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Chemistry You Can Do A Penny for Your Thoughts |
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1069 | (2) |
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Portrait of a Scientist Alfred Werner |
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1071 | |
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Problem Solving and Mathematical Operations |
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1 | (18) |
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Units, Equivalences, and Conversion Factors |
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19 | (5) |
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24 | (1) |
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25 | (1) |
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Naming Simple Organic Compounds |
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26 | (5) |
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Ionization Constants for Weak Acids at 25°C |
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31 | (1) |
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Ionization Constants for Weak Bases at 25°C |
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32 | (1) |
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Solubility Product Constants for Some Inorganic Compounds at 25°C |
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33 | (2) |
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Standard Reduction Potentials in Aqueous Solution at 25°C |
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35 | (3) |
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Selected Thermodynamic Values |
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38 | (7) |
| Answers to Problem-Solving Practice Problems |
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45 | (17) |
| Answers to Exercises |
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62 | (18) |
| Answers to Selected Questions for Review and Thought |
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80 | |
| Glossary |
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1 | (1) |
| Index |
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1 | |
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