Controlled/Living Radical Polymerization Progress in ATRP, NMP and RAFT,9780841237070

Controlled/Living Radical Polymerization Progress in ATRP, NMP and RAFT

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ISBN13: 9780841237070
ISBN10: 0841237077
Format: Hardcover
Pub. Date: 2000-07-20
Publisher(s): American Chemical Society
List Price: $223.99

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Summary

This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.

Table of Contents

Preface xi
Advances in Conventional and Controlled Radical Polymerization
Comparison and Classification of Controlled/Living Radical Polymerizations
2(25)
Krzysztof Matyjaszewski
Kinetics of Living Radical Polymerization
27(12)
Takeshi Fukuda
Atsushi Goto
Initiation and Termination Rates Associated with Free-Radical Polymerization in Extended Ranges of Temperature and Pressure
39(18)
Michael Buback
Stereochemistry in Radical Polymerization of Vinyl Esters
57(11)
Yoshio Okamoto
Kazunobu Yamada
Tamaki Nakano
Electron Paramagnetic Resonance Study of Conventional and Controlled Radical Polymerizations
68(14)
Atsushi Kajiwara
Krzysztof Matyjaszewski
Mikiharu Kamachi
Models for Free-Radical Copolymerization Propagation Kinetics
82(11)
Michelle L. Coote
Thomas P. Davis
Leo Radom
Topochemical Polymerization of Diene Monomers in the Crystalline State to Control the Stereochemistry of the Polymers
93(15)
Akikazu Matsumoto
Toru Odani
Nitroxide-Mediated Polymerization
Use of Phosphonylated Nitroxides and Alkoxyamines in Controlled/``Living'' Radical Polymerization
108(15)
C. Le Mercier
J.-F. Lutz
S. Marque
F. Le Moigne
P. Tordo
P. Lacroix-Desmazes
B. Boutevin
J.-L. Couturier
O. Guerret
R. Martschke
J. Sobek
H. Fischer
Progress Toward a Universal Initiator for Nitroxide Mediated `Living' Free Radical Procedures
123(15)
Didier Benoit
Eva Harth
Brett Helms
Ian Rees
Robert Vestberg
Marlene Rodlert
Craig J. Hawker
Nitroxide-Mediated Controlled Free-Radical Emulsion and Miniemulsion Polymerizations of Styrene
138(14)
M. Lansalot
C. Farcet
B. Charleux
J.-P. Vairon
R. Pirri
P. Tordo
Triazolinyl Radicals: Toward a New Mechanism in Controlled Radical Polymerization
152(16)
Markus Klapper
Thorsten Brand
Marco Steenbock
Klaus Mullen
Atom Transfer Radical Polymerization
Living Radical Polymerization of Styrene: RuCl2(PPh3)3 and Alkyl Iodide-Based Initiating Systems
168(14)
Yuzo Kotani
Masami Kamigaito
Mitsuo Sawamoto
Copper-Mediated Living Radical Polymerization Utilizing Biological and End Group Modified Poly(ethylene-co-butylene) Macroinitiators
182(15)
David M. Haddleton
Adam P. Jarvis
Carl Waterson
Stefan A. F. Bon
Alex M. Heming
Atom Transfer Radical Copolymerization of Styrene and Butyl Acrylate
197(14)
Gregory Chambard
Bert Klumperman
The Copper Catalyst in Atom Transfer Radical Polymerizations: Structural Observations
211(12)
Guido Kickelbick
Ulrich Reinohl
Teja S. Ertel
Helmut Bertagnolli
Krzysztof Matyjaszewski
Atom Transfer Radical Polymerization Mediated by Ruthenium(II)-Arene Complexes
223(11)
Francois Simal
Dominique Jan
Albert Demonceau
Alfred F. Noels
Polychloroalkanes as ATRP Initiators: Fundamentals and Application to the Synthesis of Block Copolymers from the Combination of Conventional Radical Polymerization and ATRP
234(14)
M. Destarac
B. Boutevin
Krzysztof Matyjaszewski
Controlled Radical Polymerization Utilizing Preformed Metal Complexes Based on Substituted Bipyridines and Terpyridines
248(15)
U. S. Schubert
G. Hochwimmer
C. E. Spindler
O. Nuyken
Reverse Atom Transfer Radical Polymerization Using AIBN or BPO as Initiator
263(15)
Wenxin Wang
Deyue Yan
Other Methods for Controlled Radical Polymerization
Synthesis of Defined Polymers by Reversible Addition-Fragmentation Chain Transfer: The RAFT Process
278(19)
Ezio Rizzardo
John Chiefari
Roshan T. A. Mayadunne
Graeme Moad
San H. Thang
Preparation of Macromonomers via Chain Transfer with and without Added Chain Transfer Agent
297(16)
John Chiefari
Justine Jeffery
Roshan T. A. Mayadunne
Graeme Moad
Ezio Rizzardo
San H. Thang
End-Group Control in Catalytic Chain Transfer Polymerization
313(21)
Johan P. A. Heuts
David A. Morrison
Thomas P. Davis
New Materials by Controlled Radical Polymerization
Synthesis of Polystyrene-Polyacrylate Block Copolymers by Nitroxide-Mediated Radical Polymerization
334(13)
Sophie Robin
Yves Gnanou
Functionalized Polymers by Atom Transfer Radical Polymerization
347(14)
Scott G. Gaynor
Krzysztof Matyjaszewski
Copolymerization of n-Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers by Conventional and Atom Transfer Radical Copolymerization
361(11)
Sebastian G. Roos
Axel H. E. Muller
Krzysztof Matyjaszewski
Quantitative Derivatizations of 1-Chloro-1-phenylethyl Chain End of Polystyrene Obtained by Quasiliving Atom Transfer Radical Polymerization
372(12)
Bela Ivan
Tamas Fonagy
Synthesis of Alternating Copolymers of N-Substituted Maleimides with Styrene via Atom Transfer Radical Polymerization
384(10)
Fu-Mian Li
Guang-Qiang Chen
Ming-Qiang Zhu
Peng Zhou
Fu-Sheng Du
Zi-Chen Li
Controlled Radical Copolymerization of Styrene and Acrylonitrile
394(14)
S. Brinkmann-Rengel
N. Niessner
Synthesis of Oligomers by Stable Free Radical Polymerization of Acrylates, Methacrylates, and Styrene with Alkoxyamine Initiators
408(19)
Helmut Keul
Dirk Achten
Birte Reining
Hartwig Hocker
Potential Impact of Controlled Radical Polymerization on Markets for Polymeric Materials
427(18)
James Spanswick
Elizabeth A. Branstetter
William F. Huber, Jr.
Indexes
Author Index
443(2)
Subject Index
445

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