Acknowledgments |
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vii | |
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Importance of Alkenes in the Chemistry of Ozone Generation in the Urban Atmosphere |
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3 | (20) |
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Typical Composition of the Hydrocarbons Present in Urban Air |
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4 | (8) |
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Relative Importance of OH, NO3, O3, and O(3P) as Reactants for Alkenes |
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12 | (4) |
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Importance of Alkenes Relative to Other Volatile Organic Compounds as Reactants for OH, NO3, and O3 |
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16 | (1) |
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Relative Importance of Individual Alkenes |
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17 | (6) |
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Reaction of Alkenes with the OH Radical |
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23 | (104) |
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Mechanisms of the OH-Alkene Reactions |
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23 | (10) |
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Measured Rate Coefficients for OH--Alkene Reactions |
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33 | (57) |
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Estimation of Rate Coefficients for OH--Alkene Reactions |
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90 | (3) |
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Major Products of the Reactions of OH with Alkenes |
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93 | (13) |
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Reactions of HOCxHyO2 Radicals Formed Following OH Addition to the Alkene Double Bond |
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106 | (7) |
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Reactions of HOCxHyO Radicals Formed from HOCxHyO2 Radicals |
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113 | (14) |
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Reactions of Alkene with the NO3 Radical |
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127 | (45) |
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Mechanisms of the NO3--Alkene Reactions |
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127 | (5) |
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Measured Rate Coefficients for NO3--Alkene Reactions |
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132 | (30) |
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Estimation of Rate Coefficients for NO3--Alkene Reactions |
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162 | (2) |
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Major Products of the Reaction of NO3 Radicals with Alkenes |
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164 | (8) |
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Reactions of Alkenes with O3 |
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172 | (64) |
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Mechanisms of the Ozone--Alkene Reactions |
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174 | (1) |
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Measured Rate Coefficients for O3--Alkene Reactions |
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174 | (57) |
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Estimation of Rate Coefficients for O3--Alkene Reactions |
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231 | (4) |
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Products and Mechanism of the Reaction of Ozone with Alkenes |
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235 | (1) |
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Reactions of Alkenes with O(3P)--Atoms and NO2 |
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236 | (111) |
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Measured Rate Coefficients for O(3P)--Alkene Reactions |
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338 | (4) |
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Products and Mechanism of Alkene--O(3P) Reactions |
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342 | (2) |
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Thermal Reactions of Alkenes with NO2 |
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344 | (3) |
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Rate Coefficients of OH, NO3, and O3 Reactions with the First-Generation Atmospheric Oxidation Products of Alkenes |
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347 | (21) |
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Reactions of OH Radicals with Oxygen-Containing Organic Compounds |
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348 | (14) |
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Reactions of NO3 Radical with Oxygen-Containing Organic Compounds |
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362 | (4) |
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Reactions of O3 with Oxygen-Containing Organic Compounds |
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366 | (2) |
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Primary Photochemical Processes in Some Important Light-Absorbing Products of Atmospheric Oxidation of the Alkenes |
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368 | (39) |
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Photolysis Model Description |
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369 | (2) |
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371 | (8) |
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379 | (7) |
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Propanal (Propionaldehyde) |
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386 | (3) |
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389 | (3) |
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392 | (3) |
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395 | (6) |
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401 | (1) |
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402 | (5) |
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Application of Findings to the Modeling of Alkene Atmospheric Chemistry |
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407 | (6) |
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Atmospheric Chemistry Modeling Methods |
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407 | (3) |
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Some Special Considerations of Chemical Mechanisms that Simulate Alkene Atmospheric Oxidation |
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410 | (3) |
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Important Areas for Further Laboratory Studies |
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413 | (9) |
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Areas of Greatest Uncertainty in the Mechanisms of the Atmospheric Oxidation of Alkenes |
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414 | (6) |
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A Qualitative Prioritization of the Research Efforts in Areas Suggested for Further Studies |
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420 | (2) |
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422 | (8) |
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Importance of Alkenes in the Chemistry of Ozone Generation in the Urban Atmosphere |
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422 | (1) |
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Reactions of Alkenes with the OH Radical |
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423 | (1) |
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Reactions of Alkenes with the NO3 Radical |
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424 | (1) |
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Reactions of Alkenes with O3 |
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425 | (2) |
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Reactions of Alkenes with O(3P)-Atoms and NO2 |
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427 | (1) |
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Rate Coefficients of OH, NO3, and O3 Reactions with the First-Generation Atmospheric Oxidation Products of Alkenes |
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427 | (1) |
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Primary Photochemical Processes in Some Important Light-Absorbing Products of the Atmospheric Oxidation of the Alkenes |
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428 | (1) |
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Application of Findings to the Modeling of Alkene Atmospheric Chemistry |
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428 | (1) |
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Important Areas for Further Laboratory Studies |
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429 | (1) |
References |
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430 | (27) |
Appendix A Nomenclature and Molecular Structure of the Alkenes |
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457 | (32) |
Appendix B Nomenclature and Structure of Some Major Products of Alkene Atmospheric Oxidation Processes |
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489 | (32) |
Author Index |
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521 | (14) |
Subject Index |
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535 | |