Renewable Raw Materials : New Feedstocks for the Chemical Industry

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Format: Hardcover
Pub. Date: 2011-04-18
Publisher(s): Vch Pub
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Summary

This contemporary overview on a major topic of the 21st century provides an emphasis on cradle-to-grave life cycle assessments of existing or conceptual processes for producing value-added fuels, chemicals, and/or materials from renewable agricultural residues, plant-derived starches and oils (lipids), lignocellulosic biomass, and plant-based industrial processing wastes. It presents the key concepts, systems, and technologies of renewable raw materials, focusing on new feed stocks for the chemical industry. Each chapter is discussed using common themes of specific raw materials, thus forming a natural progression for the entire work. The result is coverage of the topic from a wide array of aspects, emphasizing not only technical aspects but also considering the market place and socio-economic aspects. The 'go to' source for those wishing to familiarize themselves with the state of science and technology in the conversion of renewable raw materials -- exploring developments in the use of renewable feed stocks for the production of fuels, chemicals and materials to support a bio-based economy.

Author Biography

Roland Ulber studied chemistry at the University of Hanover, Germany, graduating in 1994, and where he gained his PhD in 1996 from the Institute of Technical Chemistry. He received his lecturing qualification from the same university in 2002, and has been. Professor for Bioengineering at the Technical University of Kaiserslautern since 2004. He is involved in several national and international research projects in the area of biorefineries, and is chairman of the working group on "Biotechnological Use of Renewable Resources" at the DECHEMA in Frankfurt. Professor Ulber's main research interest is the use of renewable resources as feedstock for chemical and biotechnological processes. A professor at Stuttgart University, Germany, since 2008, Thomas Hirth studied chemistry at Karlsruhe University with a focus on organic and technical chemistry, where he gained his doctorate in physical chemistry in 1992. Since then he has worked at the Fraunhofer Gesellschaft, initially as department head of environmental engineering at the Fraunhofer Institute for Chemical Technology, and since 2007 as head of the Fraunhofer Institute for Interfacial and Bioprocess Engineering. With numerous publications to his name, Professor Hirth is a member of various scientific-technical societies, such as the GDCh, DECHEMA and VDI, chair of several expert committees and a member of the council on bioeconomy. The main emphasis of his scientific work is on the material use of renewable resources and the development of biorefinery concepts for integrating chemical and biotechnological processes. An extraordinary professor at Leibniz University Hanover, Germany, since the beginning of 2010, Dieter Sell studied biology with a focus on biochemistry at Ruhruniversitt Bochum. He gained his doctorate in 1991 at the institute of chemical engineering of Dortmund University, and his lecturing qualification in 2004 from the University of Hanover in technical chemistry. From 1991 onwards he developed the bioprocess engineering working group at the Karl Winnacker Institute of DECHEMA, which he has led until 2006. This group is involved in bioelectrochemical systems, the production of biotechnological materials and in ecoefficiency analyses for biotechnical products. Also, since that same year Professor Sell has been head of the biotechnology department at DECHEMA, and an activemember of national and international committees working on the use of renewable resources in industrial biotechnology.

Table of Contents

List of Contributorp. xi
Introduction to Renewable Resources in the Chemical Industryp. 1
Plants as Bioreactors: Production and Use of Plant-Derived Secondary Metabolites, Enzymes, and Pharmaceutical Proteinsp. 7
Introductionp. 7
Renewable Resources in the Chemical Industryp. 7
Commodity Productionp. 8
Production Problemsp. 9
Natural Rubber as Compared to Synthetic Rubberp. 12
Cellulose and Other Fibersp. 12
Paper Productionp. 13
Starch Productionp. 15
Sugar Production and Improvement of Yield by Genetic Engineeringp. 16
Fine Chemicals and Drugsp. 17
Plant Cell Culturep. 17
Terpenoidsp. 17
Amino Acidsp. 18
Fatty Acid Derivativesp. 18
Plant Protectionp. 19
Small Molecule Drugsp. 19
Polyphenols and Resveratrolp. 22
Plant-Made Pharmaceuticalsp. 22
Vaccinesp. 24
Monoclonal Antibodiesp. 25
Other Therapeutic Proteinsp. 26
Methodologies for PMP Productionp. 26
Referencesp. 28
World Agricultural Capacityp. 33
Petrochemicals Todayp. 33
Renewable Chemicalsp. 34
Traditional Usesp. 34
Potential Raw Materialsp. 34
Scope for Substitutionp. 35
Agricultural Productionp. 36
Current Situationp. 36
Increasing Productionp. 40
Increasing Availabilityp. 43
Future Prospectsp. 43
Supplying the Chemical Industryp. 44
Summaryp. 45
Referencesp. 46
Logistics of Renewable Raw Materialsp. 49
Introductionp. 49
Determining Factors for the Logistics of Industrial Utilization Chains for Renewable Raw Materialsp. 50
Operating in a Natural Environmentp. 50
Characterization of Selected Renewable Raw Materialsp. 52
Oil Cropsp. 52
Sugar Cropsp. 57
Starch Cropsp. 60
Lignocellulosic Biomassp. 64
Other Biogenic Residuesp. 67
Algaep. 68
Actors and Stakeholders-Mobilization of the Renewable Raw Materialsp. 69
Processing Steps of Renewable Raw Material Logistic Chainsp. 71
Cultivation and Harvesting for Selected Types of Renewable Raw Materialsp. 71
Agricultural Productionp. 71
Forest Productionp. 75
Transportp. 79
Storagep. 81
Design and Planning of Renewable Raw Material Logistic Chainsp. 82
Determining Plant Sizes: Economies of Scale vs. Minimization of Transport Loadp. 82
Facility Location Planning and Determining the Logistical Structure of a Renewable Raw Material Utilization Chainp. 85
Consideration of Competing Utilization Pathwaysp. 86
Demand for Integrated Assessment and Planning Methods for Renewable Raw Material Logistic Chainsp. 88
Summary and Conclusionsp. 89
Referencesp. 90
Existing Value Chainsp. 95
Industrial Biotechnology Today - Main Products, Substrates, and Raw Materialsp. 95
White Biotechnology-Future Products from Today's Raw Materials?p. 97
Effects of Feedstock and Process Technology on the Production Cost of Chemicalsp. 100
Introductionp. 100
Simplified Procedure for Cost Estimationp. 102
Example: Alkenes from Petroleum Fractions and from Bioethanolp. 104
New Raw Materials for White Biotechnologyp. 105
Case Studies: Lignocellulose as Raw Material and Intermediatesp. 107
Bioethanol and Chemical Production from Lignocellulosic Biomassp. 107
Limitationsp. 110
Substratep. 110
Pretreatrnentp. 110
Composition of Biomassp. 111
Hydrolysisp. 111
Fermentationp. 112
Research and Development Potentialp. 112
Case Studies: "SCOs" as Raw Material and Intermediatep. 114
Microbial SCOsp. 114
Industrial Use of Microbial SCOsp. 114
Limitations and Research and Development Potentialp. 115
Conclusionsp. 117
Referencesp. 118
Future Biorefineriesp. 121
Introductionp. 121
Current and Future Outlook for Biofuelsp. 122
Bioethanolp. 123
Biobutanolp. 125
Biodieselp. 125
Microalgaep. 127
Chemicals from Renewable Resourcesp. 129
Succinic Acidp. 129
Aspartic Acidp. 131
Levulinic Acidp. 132
Sorbitol Add (SBA)p. 132
Glycerolp. 133
The Role of Clean Technologies in Biorefineriesp. 134
Separation Technologiesp. 134
Spercritical CO2 Extractionp. 135
Cellulose Hydrolysisp. 136
Thermochemical Processingp. 138
The Size of Future Biorefineriesp. 139
Conclusionsp. 139
Referencesp. 140
Economic and Social Implications of the Industrial Use of Renewable Raw Materialsp. 143
Introductionp. 143
Biorefinery Industry and the Development of EU Rural Areasp. 146
Overview of Different Models of Biorefinery Industryp. 146
Potential Effects of the Global Modelp. 147
Potential Effects of the Local Modelp. 149
Which Biorefinery Model for EU Rural Areas?p. 149
From Analytic to Systemic Modeling Methodology of the Biorefinery Industryp. 150
The Search for a Theoretical Framework Capable of Dealing with Novelty, Uncertainty, Ignorance, and Unpredictabilityp. 150
FCMs to Find Knowledge in Complex Systemsp. 152
Stakeholders' Perceptions of Biorefinery in Rural Areas: Issues and Lessons from the South of Italyp. 155
A Network Analysis of Stakeholders' Knowledgep. 156
Interpretation of Resultsp. 162
Determinantsp. 162
Influential Conditionsp. 164
Effectsp. 164
Concluding Remarksp. 165
Acknowledgmentsp. 166
Referencesp. 166
Biobased Products-Market Needs and Opportunitiesp. 169
Introductionp. 169
Definitionp. 170
Basic Technology for the Conversion of Renewable Raw Materialsp. 172
Classes of Bioproductsp. 172
Current Statusp. 173
Polymersp. 174
Polylactic Acidp. 174
Polyethylenep. 175
Othersp. 175
Potentialp. 176
Lubricantsp. 177
Solventsp. 179
Surfactantsp. 180
Outlook and Perspectivesp. 182
Referencesp. 185
Life-Cycle Analysis of Biobased Productsp. 187
Introduction: Why Life-Cycle Analysis of Biobased Products?p. 187
The Methodological Framework of LCAp. 188
General Goal and Framework of LCAp. 188
Phases of LCAp. 189
General Schemep. 189
Goal and Scope Definitionp. 190
Life Cycle Inventory (LCI)p. 190
Life Cycle Impact Assessment (LCIA)p. 192
Interpretationp. 196
Databases and Software for LCAp. 196
Specific Methodological Aspects for LCA for Biobased Productsp. 196
Methodological Outlinep. 196
Accounting for Land Use in LCAp. 198
Conceptual Aspects for Treatment of Land Use in LCAp. 198
Land Occupation and Land Transformationp. 198
Impacts of Land Usep. 199
LCA Studies for Biobased Products: Major Findings and Insightsp. 200
Biofuelsp. 200
Biopolymersp. 204
Products from Biotechnological Processesp. 206
Compositesp. 208
Consumer Productsp. 209
Packagingp. 210
Products for the Building Sectorp. 210
Lubricantsp. 210
Conclusionsp. 211
Referencesp. 212
Conclusionp. 217
Indexp. 221
Table of Contents provided by Ingram. All Rights Reserved.

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