
Renewable Raw Materials : New Feedstocks for the Chemical Industry
by Ulber, Roland; Sell, Dieter; Hirth, ThomasRent Textbook
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Summary
Author Biography
Table of Contents
List of Contributor | p. xi |
Introduction to Renewable Resources in the Chemical Industry | p. 1 |
Plants as Bioreactors: Production and Use of Plant-Derived Secondary Metabolites, Enzymes, and Pharmaceutical Proteins | p. 7 |
Introduction | p. 7 |
Renewable Resources in the Chemical Industry | p. 7 |
Commodity Production | p. 8 |
Production Problems | p. 9 |
Natural Rubber as Compared to Synthetic Rubber | p. 12 |
Cellulose and Other Fibers | p. 12 |
Paper Production | p. 13 |
Starch Production | p. 15 |
Sugar Production and Improvement of Yield by Genetic Engineering | p. 16 |
Fine Chemicals and Drugs | p. 17 |
Plant Cell Culture | p. 17 |
Terpenoids | p. 17 |
Amino Acids | p. 18 |
Fatty Acid Derivatives | p. 18 |
Plant Protection | p. 19 |
Small Molecule Drugs | p. 19 |
Polyphenols and Resveratrol | p. 22 |
Plant-Made Pharmaceuticals | p. 22 |
Vaccines | p. 24 |
Monoclonal Antibodies | p. 25 |
Other Therapeutic Proteins | p. 26 |
Methodologies for PMP Production | p. 26 |
References | p. 28 |
World Agricultural Capacity | p. 33 |
Petrochemicals Today | p. 33 |
Renewable Chemicals | p. 34 |
Traditional Uses | p. 34 |
Potential Raw Materials | p. 34 |
Scope for Substitution | p. 35 |
Agricultural Production | p. 36 |
Current Situation | p. 36 |
Increasing Production | p. 40 |
Increasing Availability | p. 43 |
Future Prospects | p. 43 |
Supplying the Chemical Industry | p. 44 |
Summary | p. 45 |
References | p. 46 |
Logistics of Renewable Raw Materials | p. 49 |
Introduction | p. 49 |
Determining Factors for the Logistics of Industrial Utilization Chains for Renewable Raw Materials | p. 50 |
Operating in a Natural Environment | p. 50 |
Characterization of Selected Renewable Raw Materials | p. 52 |
Oil Crops | p. 52 |
Sugar Crops | p. 57 |
Starch Crops | p. 60 |
Lignocellulosic Biomass | p. 64 |
Other Biogenic Residues | p. 67 |
Algae | p. 68 |
Actors and Stakeholders-Mobilization of the Renewable Raw Materials | p. 69 |
Processing Steps of Renewable Raw Material Logistic Chains | p. 71 |
Cultivation and Harvesting for Selected Types of Renewable Raw Materials | p. 71 |
Agricultural Production | p. 71 |
Forest Production | p. 75 |
Transport | p. 79 |
Storage | p. 81 |
Design and Planning of Renewable Raw Material Logistic Chains | p. 82 |
Determining Plant Sizes: Economies of Scale vs. Minimization of Transport Load | p. 82 |
Facility Location Planning and Determining the Logistical Structure of a Renewable Raw Material Utilization Chain | p. 85 |
Consideration of Competing Utilization Pathways | p. 86 |
Demand for Integrated Assessment and Planning Methods for Renewable Raw Material Logistic Chains | p. 88 |
Summary and Conclusions | p. 89 |
References | p. 90 |
Existing Value Chains | p. 95 |
Industrial Biotechnology Today - Main Products, Substrates, and Raw Materials | p. 95 |
White Biotechnology-Future Products from Today's Raw Materials? | p. 97 |
Effects of Feedstock and Process Technology on the Production Cost of Chemicals | p. 100 |
Introduction | p. 100 |
Simplified Procedure for Cost Estimation | p. 102 |
Example: Alkenes from Petroleum Fractions and from Bioethanol | p. 104 |
New Raw Materials for White Biotechnology | p. 105 |
Case Studies: Lignocellulose as Raw Material and Intermediates | p. 107 |
Bioethanol and Chemical Production from Lignocellulosic Biomass | p. 107 |
Limitations | p. 110 |
Substrate | p. 110 |
Pretreatrnent | p. 110 |
Composition of Biomass | p. 111 |
Hydrolysis | p. 111 |
Fermentation | p. 112 |
Research and Development Potential | p. 112 |
Case Studies: "SCOs" as Raw Material and Intermediate | p. 114 |
Microbial SCOs | p. 114 |
Industrial Use of Microbial SCOs | p. 114 |
Limitations and Research and Development Potential | p. 115 |
Conclusions | p. 117 |
References | p. 118 |
Future Biorefineries | p. 121 |
Introduction | p. 121 |
Current and Future Outlook for Biofuels | p. 122 |
Bioethanol | p. 123 |
Biobutanol | p. 125 |
Biodiesel | p. 125 |
Microalgae | p. 127 |
Chemicals from Renewable Resources | p. 129 |
Succinic Acid | p. 129 |
Aspartic Acid | p. 131 |
Levulinic Acid | p. 132 |
Sorbitol Add (SBA) | p. 132 |
Glycerol | p. 133 |
The Role of Clean Technologies in Biorefineries | p. 134 |
Separation Technologies | p. 134 |
Spercritical CO2 Extraction | p. 135 |
Cellulose Hydrolysis | p. 136 |
Thermochemical Processing | p. 138 |
The Size of Future Biorefineries | p. 139 |
Conclusions | p. 139 |
References | p. 140 |
Economic and Social Implications of the Industrial Use of Renewable Raw Materials | p. 143 |
Introduction | p. 143 |
Biorefinery Industry and the Development of EU Rural Areas | p. 146 |
Overview of Different Models of Biorefinery Industry | p. 146 |
Potential Effects of the Global Model | p. 147 |
Potential Effects of the Local Model | p. 149 |
Which Biorefinery Model for EU Rural Areas? | p. 149 |
From Analytic to Systemic Modeling Methodology of the Biorefinery Industry | p. 150 |
The Search for a Theoretical Framework Capable of Dealing with Novelty, Uncertainty, Ignorance, and Unpredictability | p. 150 |
FCMs to Find Knowledge in Complex Systems | p. 152 |
Stakeholders' Perceptions of Biorefinery in Rural Areas: Issues and Lessons from the South of Italy | p. 155 |
A Network Analysis of Stakeholders' Knowledge | p. 156 |
Interpretation of Results | p. 162 |
Determinants | p. 162 |
Influential Conditions | p. 164 |
Effects | p. 164 |
Concluding Remarks | p. 165 |
Acknowledgments | p. 166 |
References | p. 166 |
Biobased Products-Market Needs and Opportunities | p. 169 |
Introduction | p. 169 |
Definition | p. 170 |
Basic Technology for the Conversion of Renewable Raw Materials | p. 172 |
Classes of Bioproducts | p. 172 |
Current Status | p. 173 |
Polymers | p. 174 |
Polylactic Acid | p. 174 |
Polyethylene | p. 175 |
Others | p. 175 |
Potential | p. 176 |
Lubricants | p. 177 |
Solvents | p. 179 |
Surfactants | p. 180 |
Outlook and Perspectives | p. 182 |
References | p. 185 |
Life-Cycle Analysis of Biobased Products | p. 187 |
Introduction: Why Life-Cycle Analysis of Biobased Products? | p. 187 |
The Methodological Framework of LCA | p. 188 |
General Goal and Framework of LCA | p. 188 |
Phases of LCA | p. 189 |
General Scheme | p. 189 |
Goal and Scope Definition | p. 190 |
Life Cycle Inventory (LCI) | p. 190 |
Life Cycle Impact Assessment (LCIA) | p. 192 |
Interpretation | p. 196 |
Databases and Software for LCA | p. 196 |
Specific Methodological Aspects for LCA for Biobased Products | p. 196 |
Methodological Outline | p. 196 |
Accounting for Land Use in LCA | p. 198 |
Conceptual Aspects for Treatment of Land Use in LCA | p. 198 |
Land Occupation and Land Transformation | p. 198 |
Impacts of Land Use | p. 199 |
LCA Studies for Biobased Products: Major Findings and Insights | p. 200 |
Biofuels | p. 200 |
Biopolymers | p. 204 |
Products from Biotechnological Processes | p. 206 |
Composites | p. 208 |
Consumer Products | p. 209 |
Packaging | p. 210 |
Products for the Building Sector | p. 210 |
Lubricants | p. 210 |
Conclusions | p. 211 |
References | p. 212 |
Conclusion | p. 217 |
Index | p. 221 |
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