Statistical Thermodynamics of Surfaces, Interfaces, and Membranes

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Edition: Reprint
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Pub. Date: 2003-01-29
Publisher(s): CRC Press
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Summary

Understanding the structural and thermodynamic properties of surfaces, interfaces, and membranes is important for both fundamental and practical reasons. Important applications include coatings, dispersants, encapsulating agents, and biological materials. Soft materials, important in the development of new materials and the basis of many biological systems, cannot be designed using trial and error methods due to the multiplicity of components and parameters. While these systems can sometimes be analyzed in terms of microscopic mixtures, it is often conceptually simpler to regard them as dispersions and to focus on the properties of the internal interfaces found in these systems. The basic physics centers on the properties of quasi-two-dimensional systems embedded in the three-dimensional world, thus exhibiting phenomena that do not exist in bulk materials. This approach is the basis behind the theoretical presentation ofStatistical Thermodynamics of Surfaces, Interfaces, and Membranes. The approach adapted allows one to treat the rich diversity of phenomena investigated in the field of soft matter physics (including both colloid/interface science as well as the materials and macromolecular aspects of biological physics) such as interfacial tension, the roughening transition, wetting, interactions between surfaces, membrane elasticity, and self-assembly. Presented as a set of lecture notes, this book is aimed at physicists, physical chemists, biological physicists, chemical engineers, and materials scientists who are interested in the statistical mechanics that underlie the macroscopic, thermodynamic properties of surfaces, interfaces, and membranes. This paperback edition contains all the material published in the original hard-cover edition as well as additional clarifications and explanations.

Author Biography

Samuel A. Safran has been a professor in the department of Materials and Interfaces at Weizmann Institute of Science, Rehovot, Israel, since 1990 and is the first incumbent of the Steinfeld Professorial Chair. He was appointed Vice President of the Weizmann Institute in 2001 after serving as Dean of its Feinberg Graduate School for six years. He has been a senior staff physicist in the Complex Fluid Physics group at Exxon Research and Engineering, Annandale, New Jersey. His research applies the theoretical concepts of condensed matter physics to the understanding of soft matter including the structure, phase behavior, and dynamics of interfaces, membranes, and self-assembly. Specific topics include phase behavior and structure of colloidal, self-assembling and biomaterials, surface phase transitions, wetting dynamics, and the mechanics/thermodynamics of cells and membranes. He is a Fellow of the American Physical Society, on the editorial board of Langmuir, and an editor of several volumes on the physics of complex fluids.

Table of Contents

Preface xv
Mixtures and Interfaces
1(54)
Introduction
1(1)
Complex Materials and Interfaces
2(5)
Review of Classical Statistical Mechanics
7(13)
Phase Separation in Binary Mixtures
20(10)
Differential Geometry of Surfaces
30(13)
Review of Hydrodynamics
43(6)
Problems
49(4)
References
53(2)
Interfacial Tension
55(20)
Introduction
55(1)
Free Energy of Surfaces and Interfaces
56(2)
Surface/Interfacial Tension Theory
58(12)
Surface-Active Agents
70(2)
Problems
72(2)
References
74(1)
Fluctuations of Interfaces
75(22)
Introduction
75(1)
Free Energy of a Fluctuating Interface
76(3)
Thermal Fluctuations of Interfaces
79(6)
Capillary Instabilities of Interfaces
85(3)
Roughening Transition of Solid Surfaces
88(6)
Problems
94(1)
References
95(2)
Wetting of Interfaces
97(34)
Introduction
97(1)
Equilibrium: Macroscopic Description
98(6)
Long-Range Interactions: Macroscopic Theory
104(3)
Fluctuations of the Contact Line
107(4)
Equilibrium: Microscopic Description
111(10)
Dynamics of Wetting
121(6)
Problems
127(1)
References
128(3)
Interactions of Rigid Interfaces
131(44)
Introduction
131(1)
Molecular Interactions
132(3)
Van der Waals Interaction Energies
135(6)
Continuum Theory of van der Waals Forces
141(10)
Electrostatic Interactions
151(14)
Solute-Induced Interactions
165(5)
Problems
170(3)
References
173(2)
Flexible Interfaces
175(34)
Introduction
175(1)
Fluid Membranes and Surfactants
176(2)
Curvature Elasticity of Fluid Membranes
178(11)
Curvature Moduli
189(8)
Fluctuations of Fluid Membranes
197(3)
Interactions of Fluid Membranes
200(3)
Problems
203(4)
References
207(2)
Colloidal Dispersions
209(24)
Introduction
209(1)
Colloidal Dispersions
210(3)
Dispersions of Interacting Particles
213(6)
Colloid Interactions: DLVO Theory
219(2)
Long-Range Electrostatic Interactions
221(3)
Steric Interactions: Polymer Adsorption
224(3)
Structure of Colloidal Aggregates
227(3)
Problems
230(1)
References
231(2)
Self-Assembling Interfaces
233(28)
Introduction
233(1)
Micelles
234(6)
Vesicles
240(3)
Microemulsions
243(5)
Spongelike and Bicontinuous Phases
248(8)
Problems
256(1)
References
257(4)
Index 261

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