| Preface |
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| Summary |
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| Part I Theory of a single double layer |
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1 | (21) |
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Lyophobic and lyophilic colloids |
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1 | (3) |
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The electric double layer surrounding the particles |
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4 | (1) |
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The stability of lyophobic colloids |
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5 | (5) |
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10 | (3) |
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13 | (5) |
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18 | (1) |
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Van Der Waals---London attraction forces |
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19 | (1) |
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The interaction of colloidal particles |
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20 | (2) |
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Distribution of the electric charge and potential in the electrochemical double layer |
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22 | (29) |
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22 | (3) |
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Theory of the flat double layer |
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25 | (9) |
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The double layer at the interface of two liquid phases |
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34 | (3) |
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The double layer around a spherical particle |
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37 | (4) |
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Stern's theory for a flat double layer |
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41 | (5) |
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The value of the surface potential and the significance of potential determining ions. The zetapotential |
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46 | (5) |
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The free energy of a double layer system |
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51 | (15) |
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51 | (1) |
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52 | (4) |
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56 | (4) |
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On double layer interaction |
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60 | (3) |
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Appendix. On the equivalence of the two methods |
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63 | (3) |
| Part II On the interaction of two parallel flat plates |
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Charge and potential for the case of two flat double layers in interaction |
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66 | (11) |
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Interaction of two simple double layers |
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66 | (9) |
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Interaction of two double diffuse double layers |
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75 | (2) |
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The potential energy due to the interaction of two flat double layers |
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77 | (21) |
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77 | (1) |
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Potential energy via free energy |
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77 | (13) |
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Potential energy via the force |
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90 | (8) |
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The Van Der Waals---London attractive forces |
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98 | (8) |
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The attraction between two atoms |
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98 | (2) |
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The attraction between two flat plates |
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100 | (4) |
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Relativity correction to the theory of London---Van Der Waals forces |
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104 | (2) |
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Total potential energy (repulsion + attraction) for two plates, and application to colloid stability |
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106 | (29) |
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Examples of potential energy curves |
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106 | (9) |
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Graphical survey of the stability conditions |
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115 | (8) |
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Correction of the theory in respect of thermal motion of the particles |
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123 | (1) |
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The minimum in the potential curves for large distances between the plates |
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124 | (2) |
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Theory of two flat double layers on the basis of Stern's picture of the double layer |
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126 | (7) |
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133 | (2) |
| Part III On the interaction of spherical colloidal particles |
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135 | (2) |
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The potential energy of interaction for large particles with a relatively thin double layer |
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137 | (6) |
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137 | (1) |
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The repulsion for large χ a |
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137 | (3) |
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Application of the complete Gouy-Chapman equations |
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140 | (3) |
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The potential energy of interaction. when χ a is small (liner approximation) |
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143 | (17) |
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143 | (1) |
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The distribution of the electric field and the relation between charge and potential of two interacting spherical particles |
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144 | (5) |
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Potential energy of interaction of two spherical double layers |
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149 | (7) |
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Convergency and accuracy of the method used |
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156 | (1) |
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Comparison of the equations for small and large values of χ a and evaluation of the repulsion for intermediate values of χ a |
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157 | (3) |
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The attractive force and the total potential energy of interaction |
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160 | (4) |
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164 | (22) |
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164 | (5) |
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Application to the stability of colloids and related problems |
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169 | (11) |
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Introduction of the Stern correction |
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180 | (1) |
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181 | (1) |
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The minimum in the potential curves for great distances |
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182 | (4) |
| Appendix |
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Theoretical work on the stability of lyophobic colloids by previous authors |
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186 | (15) |
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186 | (1) |
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187 | (1) |
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188 | (7) |
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195 | (6) |
| Index to authors |
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201 | (2) |
| Index to subjects |
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203 | |
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